三防漆和紫外熒光劑

        三防漆通過各種操作環(huán)境為印刷電路板（PCB）和類似電氣組件提供出色的保護(hù)，保護(hù)其化學(xué)，電氣和/或機(jī)械性能。 

        涂層的可靠性根據(jù)涂層材料和使用條件而變化。如果要將PCB直接暴露在紫外線下，大多數(shù)三防漆都需要專門的加工和檢驗(yàn)程序。肉眼看不見，紫外線輻射的波長(zhǎng)在100-400納米（nm）之間。向涂層中添加UV通常熒光劑用于液體保形涂料中以用于檢查目的，但是對(duì)于聚對(duì)二甲苯使用具有顯著的缺點(diǎn)。

        Parylene一再表現(xiàn)出卓越的實(shí)用性，超越了大多數(shù)競(jìng)爭(zhēng)性涂料（包括丙烯酸，環(huán)氧樹脂，硅樹脂和聚氨酯）作為生物，消費(fèi)品，工業(yè)，醫(yī)療和軍事系統(tǒng)基材的性能，包括：納米防水網(wǎng)：http://www.yctpl.com/

·對(duì)部件形狀的適應(yīng)性，

·介電強(qiáng)度，

·耐用，靈活的部件保護(hù)，

·絕緣性能，

·無(wú)針孔均勻涂層，

·耐化學(xué)品和溶劑。

此外，與競(jìng)爭(zhēng)對(duì)手相比，聚對(duì)二甲苯涂層可以以超薄層施加，在最終產(chǎn)品上通常不會(huì)檢測(cè)到厚度水平的顯著保護(hù)。

聚對(duì)二甲苯和紫外線            

         盡管其作為保形涂層具有許多應(yīng)用和特性，但大多數(shù)聚對(duì)二甲苯品種對(duì)UV輻射的總體耐受性是有限的。雖然在室內(nèi)保持穩(wěn)定，但大多數(shù)聚對(duì)二甲苯配方不建議在直射陽(yáng)光下長(zhǎng)期操作環(huán)境下使用。

        也就是說，聚對(duì)二甲苯C和N的UV穩(wěn)定性很少超過100小時(shí); 聚對(duì)二甲苯AF-4在這方面是優(yōu)越的，當(dāng)按照現(xiàn)行的ASTM G 154標(biāo)準(zhǔn)進(jìn)行測(cè)試時(shí)，提供2,000小時(shí)或更長(zhǎng)時(shí)間的紫外線防護(hù)。這種性能水平還超過了由丙烯酸，環(huán)氧樹脂，硅樹脂和聚氨酯制成的競(jìng)爭(zhēng)性保形涂層。    

紫外熒光劑和聚對(duì)二甲苯  

         在大多數(shù)液體保形涂層處理的檢查階段使用UV熒光劑。但是，在聚對(duì)二甲苯涂層的情況下，必須注意以下原因：

·UV微量添加劑不是聚對(duì)二甲苯二聚體的一部分，必須在涂覆前加入。 

·紫外熒光材料的分子結(jié)構(gòu)大于聚對(duì)二甲苯分子。 

·Parylene材料保留了滲透掩蔽的能力，三十UV熒光劑不能滲透。 

·因此，粗略檢查可能無(wú)法檢測(cè)無(wú)涂層區(qū)域內(nèi)的UV材料。 

·該組件可以通過檢查，授權(quán)和清除其設(shè)計(jì)的功能，即使這些缺陷未被檢測(cè)到。

        常包括均勻的熒光劑，但是聚對(duì)二甲苯不具有。在UV光檢測(cè)期間，UR，AR和SR涂層發(fā)出明亮而清晰的熒光。它們清楚地表明了痕跡在涂層中的精確位置，在涂層中已經(jīng)存在并且尚未應(yīng)用。

        在這些情況下，假定向聚對(duì)二甲苯二聚體中添加UV熒光正確地指示涂層是否滲透到任何無(wú)涂層區(qū)域是錯(cuò)誤的。 

·在沉積過程中，UV熒光劑往往會(huì)隨機(jī)濺到PCB或其他組件上。 

·在某些情況下，UV熒光劑的不均勻支付可能導(dǎo)致材料隨意劃傷。 

·無(wú)論是否采取措施減輕這些可能性，其他PCB都可能完全沒有紫外熒光劑。

        通過基于這些不可靠結(jié)果的檢查來通過組件不僅會(huì)導(dǎo)致組件故障，而且還會(huì)導(dǎo)致潛在的危險(xiǎn)結(jié)果，其中通過堅(jiān)固耐用或類似的專業(yè)操作條件來依賴組件以獲得可靠的性能。     

紫外固化和聚對(duì)二甲苯

        用于保護(hù)保形涂料，粘合劑和油墨的光化學(xué)工藝，與常規(guī)固化技術(shù)相比，UV固化產(chǎn)生各種增值性能。將高強(qiáng)度紫外線照射到干燥（固化）涂層或其他物質(zhì)上，紫外線固化可以提供即時(shí)效果，提高生產(chǎn)速度，同時(shí)減少對(duì)典型設(shè)置和清理過程的需求和數(shù)量。降低的操作成本和增加的生產(chǎn)能力是許多涂料和工藝的UV固化的進(jìn)一步優(yōu)點(diǎn)。 

        在這些情況下，涂層和基材之間的優(yōu)異粘合是環(huán)保的，節(jié)省能源而無(wú)需排放控制。過程/產(chǎn)品拒絕的發(fā)生率降低提供了以下額外的好處：

·更好的附著力和粘合強(qiáng)度，

·耐用而有彈性的涂層表面,

·增強(qiáng)耐磨性/表面劃傷性，

·具有更好的防止接觸化學(xué)品和溶劑的保護(hù)。

        在程序上，UV固化過程中必不可少的光化學(xué)反應(yīng)將液體單體和低聚物與微量痕量的光引發(fā)劑混合，光引發(fā)劑隨后暴露于UV能量。在紫外線固化過程中，紫外線與特殊配方的化學(xué)物質(zhì)相互作用，比傳統(tǒng)方法更快地固化涂層。光引發(fā)劑吸收來自處理光源的紫外線能量，無(wú)論是弧光還是激光。所得到的化學(xué)反應(yīng)在幾秒鐘內(nèi)將液體涂料配方轉(zhuǎn)化為穩(wěn)定的固化膜。 

        在沉積聚對(duì)二甲苯之后，如果存在任何掩蔽區(qū)域，則去除掩蔽材料。去掩蔽區(qū)域周圍的聚對(duì)二甲苯薄膜通過去掩蔽過程最小程度地?fù)p壞是相當(dāng)普遍的。這可能導(dǎo)致聚對(duì)二甲苯的“手指”或甚至大的撕裂。有時(shí)，創(chuàng)建的邊緣必須密封，以防止任何濕氣或其他化學(xué)物質(zhì)滲入側(cè)邊的可能性。 

        可以通過施加液體保形涂層來修復(fù)這些邊緣或其他缺陷。我們經(jīng)常使用聚氨酯保形涂料，因?yàn)樗罱咏仫@示聚對(duì)二甲苯的性質(zhì)。有時(shí)我們的客戶會(huì)要求我們使用UV固化液體修飾材料。但是，由于上述原因，我們不建議使用任何與聚對(duì)二甲苯涂層配合使用的UV固化機(jī)制，因?yàn)樗鼤?huì)嚴(yán)重降低薄膜的性能。   

        盡管有效用于其目的，但這種方法與聚對(duì)二甲苯的化學(xué)氣相沉積（CVD）工藝很大程度上不相容，嚴(yán)重限制了其與聚對(duì)二甲苯的適用性。 

總  結(jié)

        不推薦使用UV熒光劑和UV固化材料作為L(zhǎng)ED器具的聚對(duì)二甲苯敷形涂料的組分。

        最重要的是要了解UV熒光劑不是原始聚對(duì)二甲苯二聚體的一部分。由于這種現(xiàn)實(shí)，組合這兩種材料改變了沉積的保形涂層的組成，污染了聚對(duì)二甲苯的純度。隨后的聚對(duì)二甲苯-UV熒光劑雜化物可以通過檢查，但通常不會(huì)比其它情況下更耐UV光。同時(shí)，由于引入了UV熒光劑污染物，因此使用聚對(duì)二甲苯保形涂層的基本導(dǎo)電，絕緣和保護(hù)性能將會(huì)降低。  

        絕對(duì)沒有數(shù)據(jù)支持這種混合薄膜的任何改進(jìn)性能，并且由于污染物的引入，UV熒光劑很可能最終會(huì)嚴(yán)重降低聚對(duì)二甲苯的性能。盡管如此，目前的證據(jù)表明，盡管大多數(shù)聚對(duì)二甲苯類型（C，D，N）的容量有限，無(wú)法為暴露于紫外光源的LED提供可靠的長(zhǎng)期保護(hù)，但已設(shè)計(jì)出可用于外部LED使用的聚對(duì)二甲苯涂層。與UV熒光劑一樣，對(duì)于聚對(duì)二甲苯是優(yōu)選的保形涂層材料的眾多應(yīng)用中的任何一種，UV可固化涂層是組合的不良選擇; 因此，它不應(yīng)該用于涂抹聚對(duì)二甲苯。

英文原文

Conformal Coatings and UV Trace

Conformal coatings provide exceptional protection for printed circuit boards (PCBs) and similar electrical assemblies, through a wide variety of operating circumstances, safeguarding their chemical, electrical, and/or mechanical properties. 

The reliability of coatings varies according to the coating material and conditions of use.  Most conformal coatings require specialized processing and inspection procedures if PCBs are to be used in direct exposure to UV light.  Invisible to the naked eye, UV radiation’s wave length registers between of 100-400 nanometers (nm).  The addition of UV trace to coatings is commonly used in liquid conformal coatings for inspection purposes, but has significant drawbacks for parylene use.

Unsuitably of UV Treatments for Parylene Conformal Coatings

Parylene has repeatedly demonstrated superior utility in comparison to most competitive coatings – including acrylic, epoxy, silicone and urethane -- surpassing their performance as a substrate covering for biological, consumer, industrial, medical and military systems, in terms of:

·        adaptability to component shape,

·        dielectric strength,

·        durable, flexible component protection,

·        insulating properties,

·        pinhole-free uniform coating, and

·        resistance to chemicals and solvents.

In addition, parylene coatings can be applied in ultra-thin layers, compared to competitors’, providing significant protection at thickness levels are generally undetected on the final product.

Parylene and UV Light            

 Despite its many applications and assets as a conformal coating, the overall resistance of most parylene varieties to UV radiation is limited.  While it remains stable indoors, most formulations of parylene are not recommended for long term use outdoors where exposure to direct sunlight is a condition of the operating environment.

That is, the UV stability of parylenes C and N seldom exceeds 100 hours; parylene AF-4 is superior in this respect, providing UV-protection for 2,000 hours or more, when tested according to the prevailing ASTM G 154 standards.   This level of performance also exceeds competing conformal coatings produced by acrylic, epoxy, silicone and urethane.    

UV Trace and Parylene       

 UV trace is used during the inspection stage of most liquid conformal coating processing.  However, in the case of parylene coatings, care must be taken for the following reasons:

·        The UV trace additive is not part of the parylene dimer and must be added prior to coating. 

·        The molecular structure of UV fluorescent materials is larger than that of parylene molecules. 

·        Parylene materials retain the ability to penetrate masking, even where those of UV fluorescents do not. 

·        Thus, cursory inspection may not detect UV material within the coating-free zone. 

·        The component may pass inspection, authorized and cleared for functions it is designed for, even as these flaws go undetected.

This is a problem for application of parylene coatings, in comparison to competitive conformal types, when a UV tracer is added.  For instance, while urethane (UR), acrylic (AR) and silicone (SR) typically include a uniform fluorescing agent in their chemistry, parylene does not.  During UV light inspection, UR, AR and SR coatings fluoresce brightly and clearly.  They plainly indicate the precise location of the trace within the coating, where it has and has not been applied.

Under these circumstances, it is wrong to presume the addition of a UV florescent to the parylene dimer correctly indicates whether or not the coating has infiltrated any coating free zones. 

·        The UV trace tends to randomly splatter onto PCBs or other assemblies during its deposition process. 

·        Uneven disbursement of the UV trace can cause haphazard streaking of the material in some instances. 

·        Other PCBs may receive no UV trace at all, regardless of the care taken to alleviate these possibilities.

Passing the component through inspection based on these unreliable outcomes can not only lead to component malfunction, but also potentially dangerous outcomes, where the component is relied on for reliable performance through ruggedized, or similarly specialized, operating conditions.     

UV Curing and Parylene

A photochemical process used to preserve conformal coatings, adhesives, and inks, UV curing generates a variety of value-added properties in comparison to conventional curing techniques.  Applying high-intensity UV light to dry (cure) coatings or other substances, UV curing can provide instant results, increasing production speed while reducing the need for and number of typical set-up and clean-up processes.  Lowered operating costs and increased production capacity are further advantages of UV curing for many coating materials and processes. 

In these cases, the consequent superior bonding between coating and substrate is environmentally friendly, saving energy without need for emissions’ controls.  The diminished incidence of process/product rejection offers the additional benefits of:

·        better adhesion and bond strength,

·        durable yet elastic coating surfaces, and

·        enhanced resistance to abrasion/surface scratching,

·        with improved protection against exposure to chemicals and solvents.

Procedurally, the photochemical reaction essential to the UV curing process mixes liquid monomers and oligomers with minute traces of photoinitiators, which are subsequently exposed to UV energy.  In the UV curing process, ultraviolet light interacts with specially formulated chemistries to cure coatings more rapidly than possible with traditional methodologies.  The photoinitiators absorb the UV energy from the process light source, either arc light or laser light.  The resultant chemical reaction converts liquid coating formulation into a stable, cured film in a matter of seconds. 納米防水網(wǎng)：http://www.yctpl.com/

After parylene has been deposited, if there were any masking areas, the masking materials are removed.  It is fairly common for the parylene film around the de-masking area to be minimally damaged by the de-masking process.  This can result in “fingers” of parylene or even large tears.  Sometimes, it is critical that the edges that were created be sealed to prevent any possibility of moisture or other chemicals penetrating the side edges. 

These edges or other imperfections can be repaired via the application of a liquid conformal coating.  We often use urethane conformal coating, as it most closely exhibits the properties of parylene.  Sometimes our customers will request that we use a UV curable liquid touchup material.  However, for the reasons outlined above, we do not recommend using any UV curing mechanism in concert with parylene coating, as it can severely degrade the film.   

While efficient for its purposes, this approach is largely incompatible with parylene’s chemical vapor deposition (CVD) process, severely limiting its suitability for use with parylene. 

Summary 

Applying UV trace and touching up with UV cured material as components of parylene conformal coatings for LED appliances is not recommended.

Of paramount importance is understanding that the UV trace is not part of the original parylene dimer.  Because of this reality, combining the two materials changes the composition of the deposited conformal coating, tainting the purity of the parylene.  The consequent parylene-UV trace hybrid may pass inspection, but will typically not be any more resistant to UV light than it would otherwise have been.  At the same time, the conductive, insulating and protective properties basic to the use of parylene conformal coatings will be diminished because of the introduction of UV trace contaminants.  

Absolutely no data supports any improved properties of this hybrid film and, as a result of the introduction of the contaminant, it is highly likely that UV trace will ultimately degrade the parylene's performance, potentially in a serious way.  Nevertheless, the current evidence shows that, despite the limited capacity of most parylene types – C, D, N – to provide dependable, longer-term protection for LEDs exposed to UV sources, parylene coatings have been devised that are useful for external LED use.  As with UV trace, UV curable coating is a bad choice for combination for any of the numerous applications where parylene is the preferred conformal coating material; thus, it should not be used for touch up with parylene.